Argentometric titration. Definition: The process of determining the quantity of a sample by adding measured increments of a titrant until the end-point, at which. automatic titrator will be used to perform the titration, and to obtain the titration curve. Background. Argentometric Titrations. In order for a titrimetric method to be . A titration in which Ag+ is the titrant is called an argentometric titration. Table provides a list of several typical precipitation titrations.

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In analytical chemistryargentometry is a type of titration involving the silver I ion. It is also possible to use indirect argentometric methods for determination of anions, that create insoluble salts with silver I for example phosphate PO4, arsenate AsO4 and chromate CrO4.

Typically, it is used to determine the amount of chloride present in a sample. The red arrows show the end points. Note See Table 9.


Chemistry Stack Exchange works best with JavaScript enabled. Methods based on precipitation of silver compounds I are called collectively argentometric methods. Because dichlorofluoroscein also carries a negative charge, it is repelled by the precipitate and remains in solution where it has a greenish-yellow color.

They adsorb on the AgCl surface, imparting a negative charge to the particles.

The quantitative relationship between the titrand and the titrant is determined by the stoichiometry of the titration reaction. Additional results for the titration curve are shown in Table 9. Chloride ions react with silver I ions to give the insoluble silver argenyometric.

Post as a guest Name. Quantitative chemical analysis 6th ed. We call this type of titration a precipitation titration. See the text for additional details. Before the equivalence point the titrand, Cl —is in excess.


Thus far we have examined titrimetric methods based on acid—base, complexation, and redox reactions. Calculate pCl after the equivalence point by first calculating the concentration of excess AgNO 3 and then calculating the concentration of Cl — using the K sp for AgCl.

A further discussion of potentiometry is found in Chapter The first reagent is added in excess and the second reagent used to back titrate the excess.

A better fit is possible if the two points before the equivalence point are further apart—for example, 0 mL and 20 mL— and the two points after the equivalence point are further apart.

The scale of operations, accuracy, precision, sensitivity, time, and cost of a precipitation titration is similar to those described elsewhere in this chapter for acid—base, complexation, and redox titrations. Email Required, but never shown. Anionic dyes such as dichlorofluorescein are attracted to the particles, and undergo a colour change upon adsorption, representing the end-point.

These methods are based on back titration of excess silver with standardized thiocyanate solution. Carbonates and phosphates precipitate with silver, and need to be absent to prevent inaccurate results. After the equivalence point, the titrant is in excess.

The sample solution is titrated against a solution of silver nitrate of aggentometric concentration. Calcium acetate “fixes” free chlorine, precipitates carbonates, and neutralizes the resultant solution.

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They are most often used for determination of chloride ions, but they can be used also for other halides bromide, iodide and some pseudohalides thiocyanate. Calculate the volume of AgNO 3 needed to reach the arventometric point.


Retrieved from ” https: There are two precipitates in this analysis: The concentration of unreacted Cl — after adding Finally, we complete our sketch by drawing a smooth curve that connects the three straight-line segments Figure 9.

Before precipitation titrimetry became practical, better methods for identifying the titratlons point were necessary.

Argentometric (silver nitrate) titrations overview

Chloride ions react with silver I atgentometric to give the insoluble silver chloride: A blank titration requires 0. By using our site, you acknowledge that you have read and understand our Cookie PolicyPrivacy Policyand our Terms of Service.

The pH also must be less than 10 to avoid the precipitation of silver hydroxide. This page was last edited on 5 Decemberat Post Your Answer Discard By argentometriic “Post Your Answer”, you acknowledge that you have read our updated terms of serviceprivacy policy and cookie policyand that your continued use of the website is subject to these policies.

In the Fajans method, named after Kazimierz Fajanstypically dichlorofluorescein is used as an indicator; the end-point is marked by the green suspension turning pink. At the beginning of this section we noted that the first precipitation titration used the cessation of precipitation to signal the end point.

Ferric acetate removes phosphates. Waylander 5, 1 10